In General > s.a. chaos; entropy
bounds; statistical mechanics; thermodynamics.
* Idea, in elementary thermodynamics:
An extensive thermodynamical function of state which grows monotonically
with E and is constant in a reversible adiabatic transformation;
Defined, up to an additive constant, by dS = dQ/T.
* History: Concept introduced
by Clausius in the 1860's; > s.a. history
of physics.
* Idea, statistical interpretation:
A measure of how spread out a classical distribution function or quantum density
matrix
is; Defined by S = –k tr
ln
,
which becomes S = k ln N when
corresponds to N equally probable microscopic states; The constant
k is identified with Boltzmann's constant.
* And ignorance: Generally,
one views entropy as a measure of our ignorance of the microscopic state of
a system; This seems to make entropy
a subjective
thing which, for a given system, depends on how much we wanted
to find out, and could be decreased if we just measured something more; This
is
so,
but in practice it is not a real problem, because S
ln N, N =
number of states compatible with our observations, and the kind of measurements
we
could think of to decrease our subjective entropy might lower N by
a factor of, say, 100; After taking the log,
this
becomes a very small amount to subtract from the previous entropy,
and
it makes no real difference; Therefore, in practice one doesn't need to
introduce
a definition of entropy different from the usual one (from R Sorkin,
meeting
1.02.1985).
* And classical / quantum
mechanics:
In classical mechanics one assumes entropies are finite, but if one takes the
→ 0
limit of any quantum entropy expression, this diverges; So classical thermodynamics
is not the
classical
limit of quantum statistical mechanics, it knows about quantum mechanics.
Information Theoretical (Shannon) Entropy > s.a. Brudno's
Theorem; information;
H Theorem;
Landauer's Principle.
$ Def: The Shannon uncertainty; For a mixed state
=
n pn |n
n|,
where {|n
}
is a complete set of states,
S = –k
n pn ln pn .
It is equivalent to the Boltzmann-Gibbs definition of entropy under
equilibrium conditions.
* Remark: Actually, we
could use the log with any base, or any other convex
function f(pn/qn),
with qn the
equilibrium probabilities; For any such f the
entropy would increase; Other properties like additivity put constraints
on f.
* Remark: Then one bit
of
information corresponds to an entropy ln 2.
@ General references: Jaynes PR(57), PR(57)
[maximum entropy principle]; Fahn FP(96)
[and thermodynamics];
Fa
JPA(98)
[generalization];
Luo
JPA(00)
[proof
of
Wehrl's
conjecture];
Chakrabarti & Chakrabarty IJMMS(05)qp [axiomatic];
Maroney qp/07 [Gibbs-Von
Neumann, motivation]; Ladyman et al SHPMP(08).
@ Boltzmann entropy: Swendsen AJP(06)
[for colloids, clarification]; Kalogeropoulos a0804 [variation
wrt energy].
@ And correlations: Van Drie mp/00; Gu
et al qp/06.
@ Wehrl information entropy: Miranowicz et al JPA(01)qp;
Piatek & Leonski
JPA(01)
[entanglement and correlations].
Kolmogorov-Sinai Entropy
* Idea: The growth rate h of
the phase space volume of a phase drop with time; By Liouville's theorem, for
a Hamiltonian system we have h =
0 if there is no coarse-graining; If V is a coarse-grained phase
space volume, we estimate V(t)
= V0 eht,
and define
h:= limV_0 to 0 limt to infty (1/t) ln V(t) .
* Remark: Notice that h is
not actually an entropy (confusing name!), but
the time derivative of the entropy S
ln V;
Related to the stability or instability (and random behavior) of the system.
* And Lyapunov exponents: Related by h =
i=1n
i
[@ Pesin UMN 77].
@ References: see Klimek & Lesniewski
AP(96)
[non-commutative Connes-Størmer entropy]; Frigg BJPS(04)
[and chaos].
Other Entropies > s.a. modified
thermodynamics [non-extensive, relativistic, etc].
* Rényi entropy: SqR
= (ln
i piq)/(1–q).
* Non-extensive entropy: Applicable when microscopic
interactions and memory are long-ranged, and extensive thermo-statistics fails;
The Tsallis
definition is Sq =
k (1–
i piq)/(q–1),
with q > 1; The Boltzmann–Gibbs expression is recovered as q
→ 1; > s.a. chaos,
cmb, stat
mech.
* Metric entropy of families
of metric spaces: The asymptotic behavior
of covering numbers.
@ Classical mechanics: Brun & Hartle PRE(99)qp/98 [histories];
McLachlan & Ryland mp/02/JMP
[algebraic].
@ Non-equilibrium: Holian PRA(86);
Kandrup JMP(87);
Martyushev et al JPA(07),
Maes & Netocny JMP(07)
[minimum entropy production].
@ Dynamical entropy: Connes et al CMP(87)*; Hudetz LMP(88);
Benatti et al JPA(04) [and discrete chaos].
@ Algebraic entropy: Bellon & Viallet CMP(99) [discrete t systems].
@ Localization entropy: Schroer ht/01 [and area law].
@ Rényi entropy:
Jizba & Arimitsu PhyA(04)cm/03 [and
Tsallis'
non-extensive S]; Masi PLA(05)
[and Tsallis, common framework]; Harremoës PhyA(06)
[operational]; Figueiredo et al PhyA(06)
[statistical, and Tsallis]; Campisi & Bagci PLA(07)
[and Tsallis ensemble]; Romera & Nagy PLA(08) [for atoms].
@ Tsallis entropy: Tsallis JSP(88);
Suyari JPA(02);
Furuichi et al JMP(04),
Furuichi JMP(06)
[properties];
Sattin PS(05)
[interpretation ito incomplete knowledge]; Piasecki PhyA(06)
[quasi-additivity]; Dukkipati et al PhyA(07)
[measure-theoretic aspects]; Lukes-Gerakopoulos
et
al PhyA(08)
[and weak chaos]; Wilc & Wlodarczyk PhyA(08)
[interpretation]; > s.a.
generalized statistical mechanics; uncertainty
relations.
@ Related topics: Lubkin IJTP(87)
[entropy of measurement]; Addison & Gray JPA(01)
[extensivity]; Pérez-Madrid
PhyA(04)
[Gibbs entropy and irreversibility]; Edwards JSP(04)
[granular or glassy systems];
Kaniadakis et al PhyA(04)
[from deformed log's]; Souza & Tsallis
PhyA(04)
[concavity and stability]; Hansen JSP(07),
Seiringer LMP(07)-a0704 [Wigner-Yanase
entropy not subadditive].
Systems > s.a. black hole
entropy; cell
complex; gravitational thermodynamics;
horizons; tilings.
@ In cosmology: Coule IJMPD(03)
[brane cosmology]; Hosoya et al PRL(04)gq [information
entropy]; Frampton et al a0801 [relative contributions]; > s.a. gr
cosmology and string
cosmology.
@ For matrices: Gadiyar et al JPA(03)mp/02 [orthogonal
and Hadamard matrices].
References > s.a. quantum entropy.
@ II: Han et al cm/97, AJP(99)
[tracing over degrees of freedom]; Styer AJP(00)
[examples
and meaning]; Lieb & Yngvason PT(00)apr
[without thermodynamics].
@ General: Jaynes AJP(65)
[Gibbs vs Boltzmann]; Wehrl RMP(78);
Martin & England
81;
Denbigh & Denbigh
85; in Sorkin PRL(86);
Mackey RMP(89);
Leff & Rex
ed-90;
Lavenda et al NCB(95); Dugdale 96 [II]; Leff AJP(96)
[and energy sharing];
Levy m.GM/06 [mathematical
interpretation]; Kozlov & Treshchev TMP(07)
[coarse-grained]; Leff FP(07)
[language and interpretation]; Scully & Scully 07 [Maxwell's demon, information,
and the quantum].
@ Properties: Kay & Kay JPA(01)mp/98 [strong
subadditivity and volume]; Touchette AJP(08)
[(non)-concavity].
@ Subsystems: Hotta & Joichi PLA(99)cm [additivity]; Baumgartner
JPA(02)mp/01.
@ Related topics: Hotke-Page & Page in(92) [and clock time]; Hall PRA(99)qp/98 [geometric,
ensemble volume]; Narnhofer & Thirring
Fiz(87) [relative entropy]; Leff AJP(99)
[dimensionless]; Dover PhyA(04)
[and scaling laws]; Mäkelä gq/06-GRF
[and area law]; > s.a. Cellular
Automaton, dissipation, Homogeneity.
Main page – Abbreviations – Journals – Comments – Other
sites – Acknowledgements
Send feedback and suggestions to bombelli at olemiss.edu – Modified
8 jul 2008