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Spring 2025 – Homework Assignment #7

Please print this sheet, sign the statement at the bottom, and use it as cover page when you submit your homework. Remember to always include a complete explanation of your reasoning, and to show all calculations.

  • 1: Quantum Pure and Mixed States for an Electron
    (a) Write down a pure quantum state for the spin of an electron in which the probability of its spin component in the z direction being found to be +ħ/2 and −ħ/2 is 1/2, represented both as a vector ψ in a 2-dimensional Hilbert space and as a density matrix ρψ, and a mixed quantum state ρ for the spin of the electron that is inequivalent to a pure state but in which the probabilities are still 1/2. (b) Calculate the mean value and fluctuation of the x component of the electron spin, Sx.
  • 2: Quantum Correction to Ideal Gas Thermodynamics
    Complete the calculation of the quantum partition function for a monatomic ideal gas we did in class, starting from the point where one expands the sum over all permutations of the N particles into an identity term, terms where only two particles are switched, etc (see the second page of the lecture notes #15), but stop after those two terms. Then evaluate the degeneracy parameter δ = ρλ3 for helium gas at STP (standard T and P) conditions. What can you conclude about whether quantum corrections to ideal gas thermodynamics for this gas are important in a normal lab setting?
  • 3: Massive Bosons in 2D: Calculate the density of states for massive bosonic particles in two spatial dimensions. Then show that in 2D Bose-Einstein condensation does not occur.
     

Aside from discussions I may have had with other students in the class about how to solve these problems, the solutions to this homework set I am submitting are entirely my own. While I was writing these solutions I did not look at anyone else's solutions, and I was not told by anyone what to write.

Name:   __________________________________   Signed:   ___________________________________

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page by luca bombelli <bombelli at olemiss.edu>, modified 4 apr 2025