Thermal Equilibrium
– Heat flow, thermal equilibrium, and how a thermometer works.
– Concept of temperature as tendency of a system to give up heat.
– Thermal expansion and the concept of absolute zero.
– Celsius, Fahrenheit and Kelvin temperature scales, TK = TC +
273 K.
The Ideal Gas and Energy Equipartition
– The ideal-gas law
PV = nRT or NkT.
– Microscopic model and relationship between T and U, Ktransl,
avg =
(3/2)kT.
– Degrees of freedom and equipartition theorem
Uthermal =
(1/2) fNkT.
– Value of f for monatomic and diatomic molecules and
solids; T dependence.
Heat, Work, and the
First Law
– Concepts of heat and work, statement of the first law of thermodynamics
ΔU = Q + W.
– Compression work, δW = –∫ P(V)
dV.
– Isothermal processes: Calculating Q and W, graphical
representation.
– Adiabatic processes: PV γ =
constant, with γ = 1+2/f ; Calculating W.
Heat Capacities
– Concept of heat capacity at constant V or P.
– Heat capacity with equipartition, CV =
(1/2) fNk , application to ideal gases.
– Dulong-Petit law for solids, CV =
3 nR.
– Relationship between heat capacities, CP =
CV + nR for an ideal gas.
– Latent heat, L = Q/M.
– Enthalpy, H = U + PV, and physical meaning;
Calculating ΔH in
various processes.
Heat Conduction
– Different mechanisms; For conduction, Fourier's heat conduction law,
Q/Δt= –kt A dT/dx. |